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设计合成了具有分子内π－π作用的锌卟啉衍生物，分子力学和核磁实验结果都证明了这种分子内π－π作用的存在，碱基与卟啉环之间的π－π作用以及卟啉环中心的锌与碱基上Ｎ 之间的二级化学键降低了主体与客体氨基酸酯的结合能力．
The zinc-porphyrin derivatives with intramolecular π-π interaction were designed and synthesized. The results of both molecular mechanics and NMR prove the existence of π-π interaction in this molecule and the π-π interaction between the base and the porphyrin ring As well as the secondary chemical bond between the zinc at the center of the porphyrin ring and the N on the base reduces the binding ability of the host to the guest amino acid ester.