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一、前言纯化学的络合滴定法在陶瓷原料的分析中得到广泛的应用,迄今已有近三十年的历史。而在电化学科学中发展的离子电极电位滴定方法由于结果处理手续较繁等原因,在我国陶瓷工业分析中的应用可以说还是一个空白。随着计算技术的发展,给填补这个空白创造了有利条件。本文叙述了几种有实际意义的电位滴定方法,并提出应用“袖珍”计算机处理实验结果的计算程序,望能起到“抛砖引玉”的作用。文中所指的电位滴定方法是广义的,它包括两种类型:典型的电位滴定法和格氏滴定法。
I. Introduction Pure complexometric titration in the analysis of ceramic raw materials has been widely used, so far, nearly three decades of history. The development of electrochemical technology in the ion electrode potentiometric titration method due to frequent processing procedures and other reasons, the application of China’s ceramic industry analysis can be said to be still a blank. With the development of computing technology, it has created favorable conditions for filling this gap. This paper describes several methods of potentiometric titration with practical significance and puts forward the calculation procedure of “pocket” computer processing experimental results. The titration method referred to herein is broad and includes two types: typical potentiometric titration and Grignard titration.