论文部分内容阅读
选择含N配体四甲基吡嗪,合成和表征了芳基钌配合物{[Ru(Cym)Cl2]2TMP}(arene=Cymene,L=2,3,5,6-Tetramethylpyrazine)。采用多种电化学方法,如循环伏安扫描法,常规脉冲伏安法,计时电流法和计时电量法研究这种钌配合物的电化学行为,测出电极反应的热力学和动力学参数,如电子转移数(n)、,扩散系数(D)和电子转移系数(α),并推导出电极的机理。
The tetramethylpyrazine containing N ligand was chosen to synthesize and characterize the aryl ruthenium complex {[Ru (Cym) Cl2] 2TMP} (arene = Cymene, L = 2,3,5,6-Tetramethylpyrazine). The electrochemical behavior of this ruthenium complex was investigated by a variety of electrochemical methods, such as cyclic voltammetry, conventional pulse voltammetry, chronoamperometry and chronoamperometry, and the thermodynamic and kinetic parameters of the electrode reaction were measured as Electron transfer number (n), diffusion coefficient (D) and electron transfer coefficient (α), and deduced the electrode mechanism.