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The title complex [nBuSn(O)O2C(OH)CPh2]6?2H2O has been synthesized by the reaction of n-BuSn(O)OH with benzilic acid in 1:1 molar radio and characterized by IR, 1H NMR spectra and elemental analysis. The crystal structure was determined by X-ray diffraction. It crystal- lizes in triclinic, space group P1 with a = 1.3543(2), b = 1.4593(2), c = 1.5293(2) nm, α = 102.075 (2), β = 115.571(2), γ = 93.308(3)°, Z = 1, V = 2.6282(7) nm3, Mr = 2550.21, Dc = 1.611 g/cm3, μ = 1.477 mm?1, F(000) = 1280, R = 0.0309 and wR = 0.0729. The structure shows a distorted octa- hedral configuration with six-coordination for the central tin atom.
The title complex [nBuSn (O) O2C (OH) CPh2] 6 · 2H2O has been synthesized by the reaction of n-BuSn (O) OH with benzilic acid in 1: 1 molar radio and characterized by IR, 1H NMR spectra and elemental Analysis of the crystal structure was determined by X-ray diffraction. It crystal-lizes in triclinic, space group P1 with a = 1.3543 (2), b = 1.4593 (2), c = 1.5293 2 = β = 115.571 (2) γ = 93.308 (3) ° Z = 1 V = 2.6282 nm3 Mr = 2550.21 Dc = 1.611 g / cm3 μ = 000) = 1280, R = 0.0309 and wR = 0.0729. The structure shows a distorted octa-hedral configuration with six-coordination for the central tin atom.