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金属-有机框架材料(MOFs)自发现以来备受关注,其独特的高孔隙率结构特性、孔径可调以及可官能化等特点,在许多领域都有潜在的应用,如储气、分离、催化和热能转化等。纳米金属-有机框架材料(NMOFs)因具有纳米尺寸,既拥有传统块状MOFs的性质,也具备特殊的物理/化学特性,表现出更为优异的性能。本文介绍了MOFs的发展,及几种经典的MOFs结构及其应用;重点论述了近年来一些重要的纳米MOFs的制备方法和应用,并对纳米MOFs在新型材料领域中的应用及其发展方向进行了展望。
Metal-organic framework materials (MOFs) have attracted much attention since their discovery, and their unique properties of high porosity, tunable pore size and functionalization have potential applications in many fields such as gas storage, separation, catalysis And heat transfer and so on. Due to their nano-size, nano-metal-organic framework materials (NMOFs) possess both the properties of traditional bulk MOFs and their special physical / chemical properties to show superior performance. This paper introduces the development of MOFs and several classical MOFs structures and their applications. The preparation methods and applications of some important MOFs in recent years are emphatically discussed. The application of MOFs in new materials and their development direction are also discussed Looking forward.