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Ti4+-mixed FePO4·xH2O precursor was prepared by co-precipitation method,with which Ti4+ cations were added in the process of preparing FePO4·xH2O to pursue an effective and homogenous doping way.Ti4+-doped LiFePO4 was prepared by an ambient-reduction and post-sintering method using the as-prepared precursor,Li2CO3 and oxalic acid as raw materials.The samples were characterized by scanning electron microscopy (SEM),X-ray diffractometry (XRD),electrochemical impedance spectroscopy (EIS),and electrochemical charge/discharge test.Effects of Ti4+-doping and sintering temperature on the physical and electrochemical performance of LiFePO4 powders were investigated.It is noted that Ti4+-doping can improve the electrochemical performance of LiFePO4 remarkably.The Ti4+-doped sample sintered at 600 ℃ delivers an initial discharge capacity of 150,130 and 125 mA·h/g with 0.1C,1C and 2C rates,respectively,without fading after 40 cycles.
Ti4 + -ixed FePO4 · xH2O precursor was prepared by co-precipitation method, with which Ti4 + cations were added in the process of preparing FePO4 · xH2O to pursue an effective and homogenous doping way. Ti4 + -doped LiFePO4 was prepared by an ambient-reduction and post-sintering method using the as-prepared precursor, Li2CO3 and oxalic acid as raw materials. Samples were characterized by scanning electron microscopy (SEM), X-ray diffractometry (XRD), electrochemical impedance spectroscopy (EIS) discharge test. Effects of Ti4 + -doping and sintering temperature on the physical and electrochemical performance of LiFePO4 powders were investigated. It is attention that Ti4 + -doping can improve the electrochemical performance of LiFePO4 remarkably. Ti4 + -doped sample sintered at 600 ° C. delivers an initial discharge capacity of 150, 130 and 125 mA · h / g with 0.1C, 1C and 2C rates, respectively, without fading after 40 cycles.