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In this work. elcctron transfer across Au supported octadecanethiolphosphatidyl choline (Au/ODT-PC) bilayers, which were modified with 7.7.8.8-tetracyanoquinodimethane (TCNQ). were investigated using electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). Results of EIS experiments show that the TCNQ molecules act as electron conductors in the bilayer. Cyclic voltammetry indicates that the TCNQ modified Au/thiol-lipid bilayers display strong asymmetrical conductivity in Fe(CN)3-/4-6 solution.