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A new coordination polymer,{[Cd(OPY)2(tdc)(H2O)]·H2O}n (OPY=4,4'-(oxybis(4,1-phenyl?ene))dipyridine,H2tdc=thiophene-2,5-dicarboxylic acid),has been synthesized hydrothermally based on a V-shaped ligand OPY.The structure was fully characterized by