Lithological and Si-O-S isotope geochemistry:constraints on the origin and genetic environment of th

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Se-rich black rock series of the Middle and Late Permian system is widely distributed in Enshi Prefecture with an exposed area of 850 km2,among which the unique Yutangba black rock series independent selenium deposit with industrial mining significance in the world is pro-duced.However,the source and metallogenic mechanisms of Se are still controversial.In general,terrestrial weath-ering and submarine hydrothermal processes are the main source end members of Si and Se,and the related siliceous rocks record the deposition process of Si and Se from different sources.The study of lithofacies and paleogeog-raphy shows that western Hubei belongs to the near east-west turn of the Yangzi platform in the Middle and Late Permian and becomes an inter-platform basin with nearly north-south direction.Therefore,the comparative study of the Yutangba deposit and the selenium-rich black rock series in the northern Shadi with high selenium content is expected to reveal the provenance evolution of the two sections in space,and further restrict the Se mineralization mechanism in the Enshi basin.From the element geo-chemistry study,the black rock series in two study areas may have formed in a transitional position of either the continental margin or continental slope,in the process of sedimentary,more terrigenous clastic materials entered.They are rich in lithophile elements V and Cr.8U > 1.0,U/Th and V/(V + Ni)ratio indicate that the Se-rich strata of black rock series in the Enshi areas occurred in an anoxic reducing environment and formed in an environ-ment between the ocean basin and the continental margin.From Si-O isotope geochemistry,the original Si source of the study area is thought to relate to a volcanic eruption,which leads to the enrichment of Si in the seawater.The determined values of S isotope in the black rock series of the two study areas both show the characteristics related to organic reduction/biogenic.
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