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One-dimensional photonic crystals with two or more structural defects are studied. We observed an interesting characteristic of transmission band structure of photonic crystals with defects using the transmission-matrixmethod simulation. The transmission states in the wide photonic band gap caused by defects revealdegeneracy and split in certain conditions. Every split state is contributed by coupling of all defects in a photonic crystal.Using the tight-binding method, we obtain an approximate analytic expression for the split frequency of photonic crystals with two structural defects.