According to time-sharing valuation principle (TSVP) of power supply, the relationships of current density and current efficiency at different acidities are obtained based on the processed data of electrolytic deposition process of zinc (EDPZ) with the least square method (LSM). Thus an optimal model of time-sharing power supply system for EDPZ is established, which has been optimized by use of an improved efficient simulated annealing algorithm (SAA). Practical results show that industrial and mining enterprises can obtain enormous economic benefits every year. According to time-sharing valuation principle (TSVP) of power supply, the relationships of current density and current efficiency at different acidities are obtained based on the processed data of electrolytic deposition process zinc (EDPZ) with the least square method (LSM). Which an optimized model of time-sharing power supply system for EDPZ is established, which has been optimized by use of an improved efficient simulated annealing algorithm (SAA). Practical results show that industrial and mining enterprises can obtain enormous economic benefits every year.