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A series of trans-3-chloro-β-lactams was synthesized stereospecifically from imines and chloroacetyl chloride or a mixture of chloroacetyl chloride and nitroacetyl chloride,prepared from vinylidene chloride and a mixture of concentrated nitric acid and sulfuric acid,in the presence of triethylamine.The reaction of vinylidene chloride and the mixed acid was investigated.The formation mechanism of chloroacetyl chloride and nitroacetyl chloride and their reaction process with imines were proposed.