The present work studied the corrosion properties around the fusion boundaries of 2.25Cr-1Mo steel with stainless steel strip overlay joints under as welded condition and after post-weld heat treatment (PWHT) in H2 S containing solution (NACE TM-01-77 standard) with different time. An in-situ observation method was introduced for evaluating corrosive progress in the fusion boundary in H2 S containing solution, that is, the samples were marked firstly at the boundary and then treated in the solution for variant time. Each time after the corrosion treatment, the observations were kept to focus at the same marked area by using scanning electron microscopy (SEM) to observe the corrosion progress. The results reveal that the fusion boundary is the worst region for corrosion resistance when comparing with other boundaries, and a broad fusion boundary has a stronger resistance for "hydrogen induced disbonding" than a narrow one.