以往含硫希夫碱金属配合物的合成，大都是配体和相应金属的盐在乙醇溶液中完成［１，２］，而用金属阳极在含配体的非水溶剂中的电化学氧化直接合成金属配合物尚未见报道。为此，本文作者首次用金属阳极电化学氧化合成了２—氯苯甲醛缩氨基硫脲（ＨＬ）与Ｃｕ（Ⅰ）、Ｆｅ... In the past, the synthesis of sulfur-containing Schiff base metal complexes, mostly the ligands and the corresponding metal salts, were performed in ethanol [1, 2] whereas electrochemical oxidation with metal anodes in ligand-containing non-aqueous solvents Synthetic metal complexes have not been reported. To this end, the author of this paper for the first time using metal anode electrochemical oxidation of 2-chlorobenzaldehyde thiosemicarbazone (HL) and Cu (Ⅰ), Fe ...