醇类化合物的碳-碳键官能团化反应一直是有机化学家们关注的焦点之一.由于醇类化合物O—H键键解离能比较高,约为440 k J/mol,使醇类化合物发生碳-碳键断裂并进行直接官能团化反应的方法目前在文献中还鲜有报道.上海科技大学物质科学与技术学院左智伟课题组利用可见光催化的方法,顺利地实现了环醇类化合物的 The carbon-carbon bond functionalization of alcohols has been one of the focuses of organic chemists.As the O-H bond dissociation energy of alcohols is relatively high, about 440 kJ / mol, the alcohol compound At present, there are few reports on the methods of carbon-carbon bond cleavage and direct functional group reaction.Zuo Zhiwei’s group at School of Material Science and Technology, Shanghai University of Science and Technology, using the method of visible light catalysis, successfully realized cyclic alcohol compounds of