A new radio spectral receiving system has been installed on the 25 m radio telescope of the Urumqi Astronomical Observatory. The back end is a surface acoustic wave chirp transform spectrometer (SAW CZT), used for the first time in radio astronomy. The calibration of the line observations has carefully been investigated for the new-type spectrometer. In order to test the feasibility of the prototype spectrometer, we observed water maser emission from a number of known Galactic sources. We describe the observed spectra of W49N, W3(OH), 2248+600 and 1909+090. We found that W49N spectrum showed high-velocity features ranging from -330 to 146 km　s-1. In comparison with the spectra observed by Medicina, the feature at the LSR velocity -52 km s-1 in the W3(OH) presented the rapid variation in flux density.