Synthesis and Crystal Structure of Bis(tert-butyl-cyclopentadienyl)Erbium Ethoxide, (t-BuCp)_2ErOEt

来源 :Journal of Rare Earths | 被引量 : 0次 | 上传用户:xingredients
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
The formation of ( t BuCp) 2ErOEt was discussed. Its single crystal structure was determined by X ray diffraction. The crystal is monoclinic, P 2(1)/ c space group, a =1.0191(2), b =1.6203(5), c =1.2118(3) nm, β =102.960(10)°, V =1.9500 (nm 3), Z =2, D c=1.566 mg·m -3 , R =0.0450, R w=0.1363. The complex is monomeric and solvent free in the solid state. The erbium ion is coordinated by two tert butyl cyclopentadienyl rings and one oxygen atom of ethoxy group to form a seven coordinated complex. The formation of (t BuCp) 2ErOEt was discussed. Its single crystal structure was determined by X-ray diffraction. The crystal is monoclinic, P2 (1) / c space group, a = 1.0191 (2), b = 1.6203 , c = 1.2118 (3) nm, β = 102.960 (10) °, V = 1.9500 (nm 3), Z = 2, D c = 1.566 mg · m -3, R = 0.0450, R w = 0.1363. The complex is monomeric and solvent free in the solid state. The erbium ion is coordinated by two tert butyl cyclopentadienyl rings and one oxygen atom of ethoxy group to form a seven coordinated complex.
其他文献
We present a 940 nm quasi-continuous wave semiconductor laser designed as a building block for high-power fiber coupled pump modules.The laser comprises a 400μ
Diphenylcarbazine citrate was synthesized and a high-speed color reaction of the new reagent with Cr (VI) was developed and used to determine trace Cr (VI) in e
Two new ent-kauranoids, named maoyecrystals A (1) and B (2), were isolated from the EtOAc extract of the dried leaves of Isodon japonica (Burman f.) Hara collec
江苏卫视的热播剧《白鹿原》,以白、鹿两家人为主线,白嘉轩为人正直无私,怀仁义之心,行事光明磊落;而鹿子霖精明能干却毫无原则,喜欢争强好胜,为了目的不择手段。但是正相反
据报道,沙特由于海湾战争巨额战费的支出及全球油价长期疲软,政府财政状况不佳,不得不采取紧缩政策,导致长期以来依赖政府支出而增长的沙特经济面临停滞状态,民间部门的消费
对同一问题的不同解法可以培养逻辑思维 ,是巩固无机化学“双基”的可取途径。 Different solutions to the same problem can cultivate logical thinking, which is a des
二战硝烟散尽已经整整半个世纪了。战后的世界经贸在50年的风雨沧桑中跋涉着。在人们以各种方式纪念二战结束50周年之际,回溯世界经贸在这期间的历程,当是另一种有益的纪念
The combustion energies of fourteen solid complexes of lanthanide nitrate with alanine were determined. The standard enthalpies of combustion, Δ c,coor(s)
期刊
A quantitative structure-property relationship (QSPR) study has been made for the prediction of the surface tension of nonionic surfactants in aqueous solution.
韩国三星电子日前宣布,将再次投资5亿美元在西安建设一个产品包装和测试工厂。三星是全球最大的手机、内存芯片和电视机生产商。该公司正在进行拓展客户多样化的努力,并加大