【摘 要】
：
提出了对氯-γ溴丙苯的合成方法,以对氯氯苄为原料制取对氯苄基氯化镁,通过镁过量解决了在四氢呋喃中的偶联问题,提高了格氏试剂的收率,此格氏试剂与环氧乙烷反应得到对氯-γ
【机 构】
：
南京林业大学化工学院 南京 210037
论文部分内容阅读
提出了对氯-γ溴丙苯的合成方法,以对氯氯苄为原料制取对氯苄基氯化镁,通过镁过量解决了在四氢呋喃中的偶联问题,提高了格氏试剂的收率,此格氏试剂与环氧乙烷反应得到对氯-γ-苯丙醇,然后在三氯甲烷助溶剂作用下,与过量的氢溴酸反应得到对氯-γ-溴丙苯,文中优化得出了最佳合成条件,为工业化生产提供了理论依据。
A method for synthesizing chloro-γ-bromopropylbenzene was proposed, p-chlorobenzylmagnesium chloride was prepared from p-chlorobenzyl chloride, the coupling problem in tetrahydrofuran was solved by magnesium excess, the yield of Grignard reagent was increased, This Grignard reagent and ethylene oxide reaction of chlorine-γ-phenylpropanol, and then in the role of chloroform flux, with excess hydrobromic acid reaction of chlorine-γ-bromopropyl benzene, the paper was optimized Out of the best synthesis conditions for industrial production provides a theoretical basis.
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