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有机锡氢化物反应活性特强 ,一直被专用于有机合成中的自由基反应药剂。但由于大部分有机锡氢化物有毒 ,并且很难与所需产品完全分离 ,因此正在努力寻觅替代品。日本京都大学材料化学系发现 ,二氯镓烷 (ＧａＨＣｌ2 )是有机锡氢化物的有效且容易分离的替代品。研究组使用三乙基
Organotin hydride reacts exceptionally well and has been dedicated to free radical reactants in organic synthesis. However, as most organotin hydrides are toxic and difficult to completely separate from the desired product, they are struggling to find alternatives. Department of Materials Chemistry, Kyoto University, Japan Found that dichloro-gallium chloride (GaHCl 2) is an effective and easily-separated alternative to organotin hydrides. The study group used triethyl