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A new complex with binuclear nickel(Ⅱ) complex [Ni2(bbimp)(CH3CH2OH)2Cl2]Cl· 4H2O (bbimp=2,6 bis[bis(2 benzimidazolylmethyl)]aminomethyl 4 methylpheno)(o)had been synthesized and characterized by elementary analysis, IR and UV. The molecular structure of the title complex was determined by X ray single crystal diffraction method. The crystal is monoclinic, space group P21/n with a=20.803(2)? , b=30.708(3)? , c=20.959(2)? , β =105.776(2)° , Z=8, V=12885(2)? 3, Dx=1.132Mg· m- 3, μ =0.755mm- 1, F(000)=4592, R1=0.1267, S=1.376. It was showed that the nickel? cation is the central ion of a distorted octahedral coordination with two N belonging to benzimidazole, a bridging phenolate O, a N of tertiary amine, a Cl anion, and an O of an ethanol molecule. Two nickel? cations in a molecular structure had the same coordinated environment. CCDC: 197601.
A new complex with binuclear nickel (Ⅱ) complex [Ni2 (bbimp) (CH3CH2OH) 2Cl2] Cl · 4H2O (bbimp = 2,6 bis [bis (2 benzimidazolylmethyl)] aminomethyl 4 methylpheno) (o) had been synthesized and characterized by elementary analysis, IR and UV. The molecular structure of the title complex was determined by X ray single crystal diffraction method. The crystal is monoclinic, space group P21 / n with a = 20.803 (2) ?, b = 30.708 , β = 105.776 (2) °, Z = 8, V = 12885 (2) 3 3, Dx = 1.132 Mg · m -3, μ = 0.755 mm -1, F (000) = 4592, R1 = 0.1267, S = 1.376. It was showed that the nickel cation is the central ion of a distorted octahedral coordination with two N belonging to benzimidazole, a bridging phenolate O, a N of tertiary amine, a Cl anion, and an O of an ethanol molecule. Two nickel? cations in a molecular structure had the same coordinated environment. CCDC: 197601.