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利用手性相转移催化剂(氯化苄基莘可宁)诱导合成了具有光学活性的炔桥钴钼双金属异核配合物,并实现了此配合物中手性四面体骨架催化二乙基锌与苯甲醛加成反应的下对称诱导,从而证实了四面体骨架手性对催化反应的不对称诱导作用.
An optically active alkyne-bridged cobalt-molybdenum bimetallic heteronuclear complex was induced by chiral phase transfer catalyst (benzylsulfonyl chloride), and the chiral tetrahedral framework-catalyzed diethylzinc Under asymmetric induction with benzaldehyde, the asymmetric induction of the catalytic reaction by the tetrahedral backbone chirality was confirmed.