论文部分内容阅读
采用水热合成法得到了新颖的过渡金属配位超分子[Co(o-pha)(phen)(H2O)3]·H2O(o-pha=o-phthalic).对该配合物进行了单晶X-射线衍射测定.结构分析表明,在晶体中存在着大量的氢键,将配合物连成了具有1D双链结构的配位超分子.同时对它的UV-VIS-NIR,IR进行了测定和分析指认.
A novel transition metal coordination supermolecule [Co (o-pha) (phen) (H2O) 3] · H2O (o-pha = o-phthalic) was synthesized by hydrothermal method. X-ray diffraction analysis. Structural analysis showed that a large number of hydrogen bonds were present in the crystal and the complex was linked into a 1D double-stranded supramolecular structure. At the same time, its UV-VIS-NIR and IR Determination and analysis of identification.