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以(NH4)6MnMo9O32和盐酸胍为前体原料,采用常规的水溶液法制备了Waugh型钼酸盐(CH6N3)6MnMo9O32·4H2O,并对其进行了红外光谱、紫外可见光谱、元素分析及单晶结构表征.晶体学参数为:四方晶系,P4(3)2(1)2空间群,a=16.51(13)A,b=16.51(13)A,c=17.40(18)A,V=4 742.4(7)A3,Z=4,D c=2.547 g·cm-3,R1=0.036 6,wR2=0.083 5(I>2σ),GOF=1.054.
Waugh-type molybdate (CH6N3) 6MnMo9O32 · 4H2O was prepared by the conventional aqueous method using (NH4) 6MnMo9O32 and guanidine hydrochloride as precursors. The infrared spectroscopy, UV-Vis spectra, elemental analysis and single crystal structure The crystallographic parameters are: tetragonal system, P4 (3) 2 (1) 2 space group, a = 16.51 (13) A, b = 16.51 (13) A, c = 17.40 18A, V = 4 742.4 (7) A3, Z = 4, D c = 2.547 g · cm -3, R1 = 0.036 6, wR2 = 0.083 5 (I> 2σ), GOF = 1.054.