【摘 要】
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It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compou
【机 构】
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Shandong Province Key laboratory of Plant Nutrition and Fertilizer,Agriculture Resources and Environ
【出 处】
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Chinese Journal of Chemical Engineering
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It is important to know how ILs(ionic liquids)influence organic reaction.In this paper,activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically.Through the study on typical organic reactions happened in ILs,such as Diels-Alder,esterification and Friedel-Crafts reaction,the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
It is important to know how ILs (ionic liquids) influence organic reactions.In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected andively analyzed systematically.Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.
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