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用溶剂热法设计、合成了4个金属-有机配合物[Mn(L~1)_4(OH)_2](1),{[MnL~1(H_2O)_4]SO_4}_n(2),[CdL~2(NO_3)_2]_n(3)和{[Co(L~2)_2](PF_6)_2}_n(4),(L~1=3,6-二(N-咪唑基)哒嗪,L~2=3,6-二(N-苯并咪唑基)哒嗪),并通过元素分析、红外、X射线单晶衍射对配合物结构进行了表征,测试结果表明配合物1具有单核结构,2为一维链结构,配合物3和4均为二维网状结构。此外,对配合物3和4的固态荧光性能及光催化的性能做了进一步研究。
Four metal-organic complexes [Mn (L 1) 4 (OH) 2] (1), {[MnL 1 (H 2 O) 4] SO 4} _n (2) and [ CdL_2 (NO_3) _2] _n (3) and {[Co (L_2) _2] (PF_6) _2} _n (4) (L-2 = 3,6-bis (N-benzimidazolyl) pyridazine) were synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. The results show that the complex 1 has Mononuclear structure, 2 is a one-dimensional chain structure, complexes 3 and 4 are two-dimensional network structure. In addition, the solid-state fluorescence properties and photocatalytic properties of complexes 3 and 4 were further studied.