【摘 要】
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The reaction of a cyclic osmacarbyne complex with sodium azide led to the formation of a ring expansion-annulation product,a unique tetrazole annulated polycyclic metallacycle.The reaction proceeds by insertion of a nitrogen atom into the metal carbon tri
【机 构】
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State Key Laboratory of Physical Chemistry of Solid Surfaces,College of Chemistry and Chemical Engin
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The reaction of a cyclic osmacarbyne complex with sodium azide led to the formation of a ring expansion-annulation product,a unique tetrazole annulated polycyclic metallacycle.The reaction proceeds by insertion of a nitrogen atom into the metal carbon triple bond and the second azide participating in the[2+3]cycloaddition.The successful isolation and characterization of metalla-azirine complex and metallapyridinium derivative strongly validated the mechanism for the formation of the title complex.The work demon-strates a new strategy to enrich the varieties of aza-metallacyclic species.
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