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A new heterometallic 4f-3d complex [Y(C6NO2H5)3(H2O)2]n(1.5nZnCl4)·nH2O(1), was synthesized via a hydrothermal reaction and structurally characterized. Complex 1 crystallized in the monoclinic system with space group P21/c: a=0.94847(9) nm, b=2.0947(