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A new 1D infinite neutral chain(Ph_3SnO_2SeOCH_2CH_3)_n(1) based on organotin and selenious acid monoethyl ester has been synthesized successfully and characterized by IR,elemental analysis,and X-ray single-crystal diffraction.In the compound 1,the Sn atom exists in slightly distorted trigonal bipyramidal geometry and the Se center is tri-coordinated with a distorted pyramidal arrangement.It is noted that the synthesis is facile and selenium oxide is directly introduced into synthesis route replacing organoseleninic acid under room temperature.
A new 1D infinite neutral chain (Ph_3SnO_2SeOCH_2CH_3) _n (1) based on organotin and selenious acid monoethyl ester has been synthesized successfully and characterized by IR, elemental analysis, and X-ray single-crystal diffraction. In the compound 1, the Sn atom exists in slightly distorted trigonal bipyramidal geometry and the Se center is tri-coordinated with a distorted pyramidal arrangement. It is noted that the synthesis is facile and selenium oxide is directly introduced into synthesis route replacing organoseleninic acid under room temperature.