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合成了2个异桥双铜配合物:[Cu_2(pfhmp)Br]·2H_2O(1)和[Cu_2(pfhmp)C_3H_3N_2]·2H_2O(2),经元素分析、红外及摩尔电导等手段推知两配合物均为烯醇式构型.变温磁化率测定结果表明,由于外源桥的影响,铜离子间的反铁磁相互作用有明显差别.
Two isosorbide copper complexes were synthesized: [Cu_2 (pfhmp) Br] · 2H_2O (1) and [Cu_2 (pfhmp) C_3H_3N_2] · 2H_2O (2) by means of elemental analysis, IR and molar conductance The results showed that the antiferromagnetic interaction between copper ions was significantly different due to the effect of exogenous bridges.