本文总结邻苯二硫酚(H_2bdt)在一系列过渡金属化合物中的结构规律,并报道在三丁基膦作用下簇合物Fe+3(bdt)_3(Pbu_3~n)_3,的生成反应。化合物属三斜晶体的P空间群,单胞参数:a=13.283(3),b=20.115(5),c=13.156(3),α=90.33(2),β=116.47(1),γ=92.19(2)°,Z=2,d_c=1.26g/cm~3;结构以直接法解出,以I>4σ(I)的4122个独立衍射点进行计算,最终收敛至R(R_w)=0.053(0.060)。化合物有较强的顺磁性。 This article summarizes the structural regularities of phthalodithiol (H 2bdt) in a series of transition metal compounds and reports the formation reaction of the cluster complex Fe + 3 (bdt) 3 (Pbu_3 ~ n) _3 under the action of tributylphosphine . The compound is a triclinic P-space group with unit cell parameters of a = 13.283 (3), b = 20.115 (5), c = 13.156 (3), α = 90.33 (2), β = 116.47 = 92.19 (2) °, Z = 2 and d_c = 1.26g / cm ~ 3. The structure was solved by direct method and calculated with 4122 independent diffraction points of I> 4σ (I) = 0.053 (0.060). The compound has a strong paramagnetic.