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设计合成了三个含有极性基团的二茂铁氮杂环衍生物,通过1H NMR、FT-IR和质谱对目标产物进行了结构表征。利用差热分析(DTA)和热重(TG)研究了在高氯酸铵(AP)中分别添加5%目标化合物后的热分解性能,发现添加二茂铁氮杂环衍生物后,AP的第二个放热峰温度可提前89.10℃,两个放热峰的距离可缩小至25.82℃。
Three ferrocene nitrogen derivatives containing polar groups were designed and synthesized. The structures of the target products were characterized by 1H NMR, FT-IR and mass spectra. Thermal decomposition (DTA) and thermogravimetry (TG) were used to investigate the thermal decomposition of 5% target compounds in ammonium perchlorate (AP). The results showed that after addition of ferrocene nitrogen derivatives, The second exothermic peak temperature can advance 89.10 ℃, the distance between the two exothermic peaks can be reduced to 25.82 ℃.