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选用苯乙烯(St)、丙烯酸丁酯(BA)和少量的N,N—二甲基,N—丁基,N—(3—甲基丙烯酰胺基)丙基溴化铵(DBMPA),以阳离子自由基型引发剂进行无皂乳液聚合,合成了稳定的无皂阳离子共聚物乳液,用粒度分布仪表征了胶平均直径、数目,用离子交换—电导滴定分析胶粒表面性质;通过表面张力、DSC等分析了胶乳的稳定性和胶膜的结构性能。
Styrene (St), butyl acrylate (BA) and a small amount of N, N-dimethyl, N-butyl and N- (3- methacrylamido) propyl ammonium bromide (DBMPA) Cationic free radical initiator was used for soap-free emulsion polymerization to synthesize a stable soap-free cationic copolymer emulsion. The average diameter and number of the gel were characterized by particle size distribution analyzer. The surface properties were analyzed by ion exchange-conductometric titration. , DSC and other analysis of the stability of the latex and the structural properties of the film.