1970年,杂多化合物[(Y y-)M m+O5X x+O4(W or Mo)11O30](12-m-x+y)-被Baker和Figgis确定,同时展示了许多Y的功能化[1]。1984年,Pope等人首先发现这些化合物可以在相转移试剂的作用下,由水相转移到非极性溶剂中,从而失去簇表面配位水,进而可被一些配体配位[2]。1986年,Hill等人又首次研究了这些取代型杂多酸的催化性能[3]。由此开辟了杂多酸的相转移及其非水化学的领域,尤其是配位水被一些有机配体取代后,极大 In 1970, the heteropoly compound [(Y y-) M m + O5X x + O4 (W or Mo) 11O30] (12-m-x + y) - was determined by Baker and Figgis and many Y functionalizations [1]. In 1984, Pope et al. First discovered that these compounds could be transferred from the aqueous phase to the non-polar solvent under the action of phase transfer reagents, thus losing coordination of water on the surface of the cluster, which may be coordinated by some ligands [2]. In 1986, Hill and others for the first time studied the catalytic properties of these substituted heteropoly acids [3]. This opens up the field of heteropolyacid phase-transfer and its non-aqueous chemistry, especially when coordination water is replaced by some organic ligands