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最近几年来电化学的研究越来越趋向于采用通常的电化学技术与就地或非就地表面分析技术相结合.这主要是由于传统电化学技术只能测量电极界面所有过程的总和,不能给出电极界面存在物质分子水平的特征.它对界面吸附分子的结构形态只能进行间接的猜测.就地方法在研究分子特性方面起着重要的作用,因为它能表征在电场存在下界面中的电极和溶液的本质和结构,而非就地的方法只能给出关于
In recent years, electrochemical research increasingly tends to use the usual electrochemical technology and in situ or non-surface analysis of the combination of technology, mainly due to the traditional electrochemical technology can only measure the electrode interface, the sum of all the processes can not Given the molecular nature of the interface at the electrode, it is only indirectly speculative about the morphology of the adsorbed molecules on the surface. The in situ method plays an important role in the study of molecular properties because it characterizes the interface in the presence of an electric field The nature and structure of the electrode and solution, whereas non-native methods can only give a clue about