Vapor-liquid equilibrium properties for confined binary mixtures involving CO2, CH4, and N2 from Gi

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蒸汽液体阶段图,共存密度,相对轻快和蒸发热含量上的稳固液体的相互作用的效果为 CO2-CH4, CO2-N2 和 CH4-N2 的限制二进制系统被调查了。吉布斯整体蒙特卡罗(GEMC ) 模拟结果显示监禁和稳固液体的相互作用在蒸汽液体平衡性质上有重要影响。监禁和稳固液体的相互作用的力量让 p-x i 阶段图移动更高迫使区域。他们也让二阶段的区域对各二进制的混合变得更狭窄。稳固液体的相互作用的力量能在共存液体和蒸汽密度引起增加,并且为学习的系统引起相对轻快和蒸发热含量的减少。当毛孔宽度被减少,二进制混合的二
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