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用中-四(对二甲基丙磺基胺基)苯基卟啉作光敏剂,在电子给体三乙醇胺(TEOA)和电子受体甲基紫精(MVI_2)存在的情况下,研究了TEOA/MeTPS/MV ̄(2+)/DMSO+H_2O(V/V=80:20)体系的光敏化还原MV ̄(2+)动力学,并由动力学参数a,光诱导时间t_i,初始反应速率υ_0来衡量光敏剂的优劣。
In the presence of electron donor triethanolamine (TEOA) and electron acceptor methyl viologen (MVI_2), a novel photosensitizer was synthesized by using tetrakis (p-dimethylpropanesulfonylamino) phenylporphyrin The kinetics of photosensitized reduction was investigated by kinetic parameters a, photoinduced time t_i and initial reaction rate υ_0, using TEOA / MeTPS / MV¯ (2 +) / DMSO + H_2O solution with V / V = 80:20 Measure the pros and cons of photosensitizers.