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A novel mixed-valent heterometallic pentanuclear CoIII3CoIIDyIII cluster has been rationally assembled taking advantage of a bifunctional ligand with o-vanillin and tripodal tris(hydroxymethyl)aminomethane units. This unique heterometallic cluster represents a rare example of T-shaped molecules exhibiting slow magnetic relaxation.
A novel mixed-valent heterometallic pentanuclear coIII3CoIIDyIII cluster has been rationally assembled taking advantage of a bifunctional ligand with o-vanillin and tripodal tris (hydroxymethyl) aminomethane units. This unique heterometallic cluster represents a rare example of T-shaped molecules exhibiting slow magnetic relaxation.