制备了单烷基羧酸型和磺酸型钛酸酯氮配位与磷配位的配合物.用 XPS 法证明有N→Ti 或 P→Ti 配位键生成,并从化学位移量推测了键的强度,磺酸型较羧酸型易配位,羟基取代胺的氮配体配位较容易发生;磷配位由于存在 Ti→P的反馈作用,使化学位移不如氮配位明显.此外,异丙基钛酸酯与乙醇胺的反应物,证明分子内有 N→Ti 配位键生成. The complexes of nitrogen coordination and phosphorus coordination of monoalkylcarboxylic acid and sulfonic acid titanate were prepared.It was proved by XPS that N → Ti or P → Ti coordination bond was formed and deduced from the chemical shift The strength of the bond, the sulfonic acid type is easier to coordinate than that of the carboxylic acid type, and the coordination of hydroxyl-substituted amine is more likely to happen. The coordination of phosphorus due to the feedback of Ti → P makes the chemical shift worse than that of nitrogen. , Isopropyl titanate and ethanolamine reactants to prove that there is N → Ti coordination bond in the molecule.