【摘 要】
：
CB[n](n= 6-8) is a family of synthetic macrocyclic host molecules composed of n glycoluril units,which can be employed as molecular reactor.N-Phenyloxypropyl-N
【机 构】
：
State Key Laboratory of Fine Chemicals, School of Chemistry, Dalian University of Technology,Key Lab
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
CB[n](n= 6-8) is a family of synthetic macrocyclic host molecules composed of n glycoluril units,which can be employed as molecular reactor.N-Phenyloxypropyl-N’-ethyl-4,4’-bipyridium(1) was designed to form a host-guest inclusion complex with CB[n](n = 6-8),subsequently,the bromination reaction of 1 and its corresponding inclusion complexes was investigated in this work.In the case of 1/CB[8],the folded including mode is quite helpful to acquire 1-bormination product completely through intramolecular charge transfer(ICT),and CB[8]can provide a safe bromination environment for 1.
CB [n] (n = 6-8) is a family of synthetic macrocyclic host molecules composed of n glycoluril units, which can be employed as molecular reactor. N- Phenyloxypropyl-N’-ethyl-4,4’-bipyridium ) was designed to form a host-guest inclusion complex with CB [n] (n = 6-8), subsequently, the bromination reaction of 1 and its corresponding inclusion complexes was investigated in this work. In the case of 1 / CB [ 8], the folding including mode is quite helpful to acquire 1-bormination product completely through intramolecular charge transfer (ICT), and CB [8] can provide a safe bromination environment for 1.
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