以邻 /对氯苯甲醛为主要原料合成了 6个四氯取代四苯基金属卟啉类化合物 ,其中 4个是尚未见文献报道的新化合物。并用红外、紫外可见光谱、质谱等分析手段对其主要基团及结构进行了表征 ,证明其结构正确。 Six ortho-p-chlorobenzaldehydes as main raw materials were synthesized six tetrachloro-substituted tetraphenylporphyrin compounds, of which four have not been reported in the literature of new compounds. The main groups and their structures were characterized by IR, UV-visible spectrum and mass spectrometry, which proved their structures were correct.