【摘 要】
：
A novel binucleus complex [Cd2(phen)4(adip)(NO3)2] (phen = phenanthroline, H2adip = adipic acid) has been synthesized by the reaction of phen and H2adip with ca
【机 构】
：
Laboratory of Coordination Chemistry,School of Resource & Civil Engineering
【基金项目】
：
辽宁省教育厅资助项目;Foundation of Excellent Personal of Shenyang Institute of Chemical Technology
论文部分内容阅读
A novel binucleus complex [Cd2(phen)4(adip)(NO3)2] (phen = phenanthroline, H2adip = adipic acid) has been synthesized by the reaction of phen and H2adip with cadmium(II) salt. Elemental analysis, IR spectra and X-ray crystal structure analysis were carried out to determine the crystal structure of the title complex. The crystal belongs to triclinic, space group (P1-) with a = 9.638(7), b = 10.315(7), c = 13.109(10) (A), α = 88.305(11), β = 69.011(11), γ = 75.818(11)°, C27H20N5O5Cd, Mr = 606.88, Z = 2, V = 1177.2(14) (A)3, Dc = 1.712 g/cm3, μ = 0.979 mm-1, -8≤h≤11, -12≤k≤12, -10≤l≤15, F(000) = 610, Rint = 0.0314, R = 0.0739 and wR = 0.1922 (I > 2σ(I). The cadmium atom is seven-coordinated in a distorted pentagonal bipyramidal configuration. The complex forms a 2-D supramolecular framework by C-H…O weak interactions and π-π stacking of neighbouring phen ligands.
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