用高分子催化剂对异丙苯的氧化进行催化已有文献报道,1973年Hara等曾用Fe-Cu混合金属聚酞菁催化异丙苯的氧化,得到的产物是异丙苯氢过氧化物。1975年,Kurusu等用高分子席夫碱-锰(钴)金属螯合物对异丙苯的氧化进行催化,这种催化剂可进一步分解异丙苯氢过氧化物,最后得到苯酚和丙酮。我们合成了含有Ni~(2+)、Mn~(2+)、Mg~(2+)、Cu~+、Rh~(3+)等过渡金属离子的多聚金属卟啉,以其作 Catalytic oxidation of cumene with polymer catalyst It has been reported in the literature that in 1973 Hara et al had catalyzed the oxidation of cumene with Fe-Cu mixed metal polyphthalocyanine. The product obtained was cumene hydroperoxide. In 1975, Kurusu et al. Catalyzed the oxidation of cumene with a polymer Schiff base-manganese (cobalt) metal chelate. This catalyst further decomposed cumene hydroperoxide and finally gave phenol and acetone. We have synthesized poly-metalloporphyrins containing transition metal ions such as Ni 2+, Mn 2+, Mg 2+, Cu 2+, Rh 3+,