Et2AlCl-Mediated Reaction of α-4(20)-Epoxy-5α -hydroxy Taxinine B

来源 :中国化学快报 | 被引量 : 0次 | 上传用户：Disama

【摘要】

：

An α-4(20)-epoxy-5α -hydroxytaxinine β 1, when treated with diethylaluminum chloride, underwent reactions involving intramolecular substitution along with de

【作者】

：

Qian CHENG Takayuki ORITANI To

【机构】

：

Laboratory of Applied Bioorganic Chemistry

【出处】

：

中国化学快报

【发表日期】

：

2004年期

【关键词】

：

Antitumour compounds taxoides epoxide diethylaluminum chloride

【基金项目】

：

Scientific reserch from the Ministry of Education, Science and Culture of Japan

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An α-4(20)-epoxy-5α -hydroxytaxinine β 1, when treated with diethylaluminum chloride, underwent reactions involving intramolecular substitution along with deacetylation or addition leading to new rings. Two novel 1-deoxy compounds 2 and 3 were isolated and fully characterized.

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Et2AlCl-Mediated Reaction of α-4(20)-Epoxy-5α -hydroxy Taxinine B

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