【摘 要】
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The title compound was obtained by the flux method and its structure was determined.It crystallizes in monoelinic,space group P2/c with a=11.0024(17).b=9.2979(1
【机 构】
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Institute of Condensed Physics and Materials
论文部分内容阅读
The title compound was obtained by the flux method and its structure was determined.It crystallizes in monoelinic,space group P2/c with a=11.0024(17).b=9.2979(14),C=14.500(2)(A),β=110.879(2)°.V=1385.9(4)(A)3,Z=4,Mr=908.38,F(000)=1592,=19.601 mm-1,Dc=4.353 g/cm3,the final R=0.0481 and wR=0.1257 for 2532 observed reflections with I>2σ(I).The Rb3La3(BO3)4 structure Can be viewed as a 3-dimensional scaffold-like framework constructed by La-O polyhedra and BOs groups.Two Rb+ ions locate in a channel along the a direction and the rest one in a cavity.
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