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在０．３６ｍｏｌ／ＬＨＣｌ介质中，有十二烷基磺酸钠（ＳＤＳ）存在下，Ｚｒ（Ⅵ）与槲皮素（Ｑｕ）和８－羟基喹啉－５－磺酸（Ｈ２ＱＳ）形成四元荧光络合物。其组成比为ｎＺｒ：ｎＱｕ：ｎＨ２ＱＳ：ｎＳＤＳ＝１：１：２：１。激发与发射波长λｅｘ＝４５０ｎｍ和λｅｍ＝５００ｎｍ时，体系荧光强度最大。线性范围为０～２４ｍｇＺｒ／Ｌ，检出限为５６μｇ／Ｌ。方法用于岩石中微量锆的测定，结果满意。
In the presence of sodium dodecyl sulfate (SDS), Zr (¢ ö) and quercetin (Qu) and 8-hydroxyquinoline-5-sulfonic acid Element fluorescent complex. The composition ratio is nZr: nQu: nH2QS: nSDS = 1: 1: 2: 1. When excitation and emission wavelength λex = 450nm and λem = 500nm, the fluorescence intensity of the system is the highest. The linear range was 0 ~ 24mgZr / L, the detection limit was 56μg / L. The method is applied to the determination of trace zirconium in rock with satisfactory results.