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Two new three-dimensional supramolecular complexes,namely,[Cd(cba)2(bib)]n(1)and [Zn(cba)2(bib)]2n(2)(Hcba =2-chlorinebenzoic acid,bib =1,4-bis(imidazol-1-yl)-butane) were hydrothermally designed and synthesized.Their structures were determined by element