【摘 要】
：
A novel transition-metal ion coordination-linked network compound {Na4[Co- (H2O)2(NH2NH2)2Mo8O27]·16H2O}n 1 was synthesized by the reduction reaction of Na2MoO
【机 构】
：
State Key Laboratory of Structural Chemistry,Fujian University of Technology
论文部分内容阅读
A novel transition-metal ion coordination-linked network compound {Na4[Co- (H2O)2(NH2NH2)2Mo8O27]·16H2O}n 1 was synthesized by the reduction reaction of Na2MoO4( 2H2O, NH2NH2(2HCl and Co(Oac)2·4H2O in aqueous solution at ambient temperature and structurally characterized. Crystal data for 1: triclinic system, space group P-1, a = 9.5544(2), b = 9.8640(2), c = 11.6338(3)(°A), α = 103.3790(10), β = 100.5600(10), γ = 96.2750(10)o, V = 1035.32(4)(°A)3, Z = 1, Dc = 2.789 g/cm3 and R = 0.0453. The X-ray crystal structure analysis shows that 1 is constructed by octamolybdate anions linked via corner-sharing interactions and hetero-metal links into the polymeric anionic sheet [Co(H2O)2(NH2NH2)2Mo8O27]n4n-, and further allied by [Na4(H2O)12]n4n+ sodium chains into a 3D framework with z-shaped channels. The mag-netic study of compound 1 indicates that weak antiferromagnetic coupling interaction occurs be-tween the cobalt centers.
其他文献
A direct approach in the study of soliton perturbations has been developed, based on the method of separation of variables in our previous papers . In this pape
A novel fibroin modified electrode with ion recognition was reported. The membrane with isoelectric point of pH 4.5, was modified on graphite and carbon fiber e
Atomic force microscopy (AFM) was used to study the competitive adsorption between bovine serum albumin (BSA) and type Ⅰ collagen on hydrophilic and hydrophobi
The sensitivity and selectivity to H2 of a new In2O3-based gas sensor were improved significantly by surface chemical modification. A dense layer of SiO2 near t
The reaction of [Et4N]2[Mo2(SC6H11)2(CO)8] and I2 in MeCN affords a new dinu- clear molybdenum(Ⅰ) complex [Mo2(SC6H11)2(CO)6(CH3CN)2] 1 (Mr = 672.46). The crys
Two new steroidal glycosides were isolated from the Chinese medicinal plantCaryopteris terniflora. The spectroscopic and chemical evidences revealed that their
Lie group technique for solving differential-difference equations is applied to a new (2+1)-dimensional Toda-like lattice. An infinite dimensional Lie algebra a
Based on the Dyson-Schwinger approach, a method for obtaining the small current quark mass effect on the dressed gluon and quark propagator is developed. A comp