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A complex [Cd(NCS)2(Vim)4] (where Vim=1-vinylimidazole) was synthesized and it’s crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21/c with the parameters: a=0.858 50(17) nm, b=0.909 90(18) nm, c=1.782 3(4) nm, β=100.14(3)°, V=1.370 5(5) nm3, Z=2. In the structure, each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS-anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was a
A complex [Cd (NCS) 2 (Vim) 4] (where Vim = 1-vinylimidazole) was synthesized and it’s crystal structure was determined by X-ray diffraction technique. The compound crystallizes in the Monoclinic space group P21 / c with the parameters : a = 0.858 50 (17) nm, b = 0.909 90 (18) nm, c = 1.782 3 (4) nm, β = 100.14 (3) °, V = 1.370 5 the structure of each Cd atom is coordinated by four 1-vinylimidazole ligands and a pair of monodentate isothiocyanic groups, affording a compressed octahedral CdN6 core. The NCS-anions are trans and four N atoms from the 1-vinylimidazole ligands define the equatorial plane. From the cyclic voltammogram measurement in H2O, we know that the electrode reaction was a