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SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX [Cu_2(CH_3COO)_4(C_8H_(11)NO)_2] · (C_6H_(11)NO)_2 · (C_8H_(12)), where C6H11 = caprolactam, Mr = 900. 07, triclinic,space group P1, a = 11. 103(4), b= 11. 865(6), c=9. 912(3)(?), α=94. 85(4), β=115.20(2), γ=103. 25(4)°, V = 1125(2)(?)3, Z = l, Dx = 1. 33g. cm-3, λ(MoKa) = 0. 71069(?), T = 295K , μ = 10. 45cm-1, F(000) = 478, final R=0. 063 for 2098 observed reflections with I>3σ (I). The two Cu atoms in the molecule are held together by four carboxylate groups. Each Cu atom is bound in a square-pyramidal configuration to four carboxyl oxygen atoms and to the O atom of a caprolactam molecule.
SYNTHESIS AND CRYSTAL STRUCTURE OF COMPLEX [Cu_2 (CH_3COO) _4 (C_8H_ (11) NO) _2] · (C_6H_ (11) NO) _2 · (C_8H_ (12)) where C6H11 = caprolactam, Mr = 900. 07, triclinic , space group P1, a = 11.103 (4), b = 11. 865 (6), c = 9.912 (3) (?),? = 94.85 (4),? = 115.20 (2) , γ = 103.25 (4) °, V = 1125 (2) (?) 3, Z = l, Dx = 1.33g.cm-3, λ (MoKa) = 0. 71069 (?), T = 295K, μ = 10. 45cm-1, F (000) = 478, final R = 0.063 for 2098 observed reflections with I> 3σ (I). The two Cu atoms in the molecule are held together by four carboxylate groups. Each Cu atom is bound in a square-pyramidal configuration to four carboxyl oxygen atoms and to the O atom of a caprolactam molecule.