【摘 要】
：
Acetonylacetone 1 was treated with thiourea, aniline, glycine and glutamic acid to give pyrrole derivatives 2, 3, 5, and 9 by Paal-Knorr reaction, respectively.
【机 构】
：
National Tobacco Cultivation
【基金项目】
：
We are grateful to the State Tobacco Monopoly Bureau;Henan Province Office of Education of China;Technology Bureau of Zhengzhou
论文部分内容阅读
Acetonylacetone 1 was treated with thiourea, aniline, glycine and glutamic acid to give pyrrole derivatives 2, 3, 5, and 9 by Paal-Knorr reaction, respectively. Then 3 was successfully transformed into the related pyrrole derivative 4 by Mannich reaction.Compounds 6, 7 and 8 were obtained by reacting 5 with phenethyl alcohol, phenylallylic alcohol and leaf alcohol by esterification reactions, respectively. The structures of all new products were elucidated by IR, NMR and HRMS spectra.
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